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Hydrogeochemical characteristics and geothermometry of hot springs in the Altai region, Mongolia

Bolormaa Chimeddorj, View ORCID ProfileDolgormaa Munkhbat, View ORCID ProfileBattushig Altanbaatar, Oyuntsetseg Dolgorjav and View ORCID ProfileBolormaa Oyuntsetseg
Geochemistry: Exploration, Environment, Analysis, 21, geochem2021-016, 25 October 2021, https://doi.org/10.1144/geochem2021-016
Bolormaa Chimeddorj
1Department of Chemistry, School of Arts and Sciences, National University of Mongolia, Ulaanbaatar 14201, Mongolia
2Department of Chemical–Biology, School of Natural Science and Technology, Khovd University, Peace Avenue, 164300 Khovd Province, Mongolia
Roles: [Data curation (Lead)], [Formal analysis (Lead)], [Investigation (Lead)], [Validation (Equal)], [Writing – original draft (Lead)], [Writing – review & editing (Lead)]
  • Find this author on Google Scholar
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Dolgormaa Munkhbat
3Department of Chemical and Biological Engineering, School of Engineering and Applied Sciences, National University of Mongolia, Ulaanbaatar 14201, Mongolia
Roles: [Data curation (Equal)], [Formal analysis (Supporting)], [Investigation (Equal)], [Writing – original draft (Equal)], [Writing – review & editing (Equal)]
  • Find this author on Google Scholar
  • Search for this author on this site
  • ORCID record for Dolgormaa Munkhbat
Battushig Altanbaatar
4Mineral Resources and Petroleum Authority of Mongolia, Ulaanbaatar, Mongolia
Roles: [Formal analysis (Supporting)], [Software (Supporting)], [Visualization (Supporting)], [Writing – original draft (Supporting)]
  • Find this author on Google Scholar
  • Search for this author on this site
  • ORCID record for Battushig Altanbaatar
Oyuntsetseg Dolgorjav
5Mongolian Academy of Sciences, Institute of Chemistry and Chemical Technology, Ulaanbaatar, Mongolia
Roles: [Data curation (Supporting)], [Methodology (Supporting)], [Validation (Equal)], [Writing – review & editing (Supporting)]
  • Find this author on Google Scholar
  • Search for this author on this site
Bolormaa Oyuntsetseg
1Department of Chemistry, School of Arts and Sciences, National University of Mongolia, Ulaanbaatar 14201, Mongolia
Roles: [Conceptualization (Lead)], [Data curation (Equal)], [Funding acquisition (Supporting)], [Methodology (Lead)], [Project administration (Lead)], [Supervision (Lead)], [Writing – original draft (Equal)], [Writing – review & editing (Supporting)]
  • Find this author on Google Scholar
  • Search for this author on this site
  • ORCID record for Bolormaa Oyuntsetseg
  • For correspondence: [email protected]
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Article Figures & Data

Figures

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  • Fig. 1.
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    Fig. 1.

    Hydrogeological regions and locations of hot springs in Mongolia.

  • Fig. 2.
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    Fig. 2.

    Geological setting of the hot spring area in the Mongolian Altai range.

  • Fig. 3.
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    Fig. 3.

    Piper diagram of the major chemical compositions of hot springs in the Mongolian Altai region.

  • Fig. 4.
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    Fig. 4.

    Gibbs diagram for hot springs in the study area.

  • Fig. 5.
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    Fig. 5.

    X-ray diffraction analyses of rock samples.

  • Fig. 6.
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    Fig. 6.

    Na–K–Mg ternary diagram (Giggenbach 1988).

  • Fig. 7.
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    Fig. 7.

    Conceptual model for geothermal water (Chikhertei).

Tables

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    Table 1.

    Equations used in the geothermometer calculations

    GeothermometerEquation (T in °C)Reference
    QuartzT=13095.19−log⁡S−273.15Fournier (1977)
    QuartzaT=15225.75−log⁡S−273.15Fournier (1977)
    ChalcedonyT=11124.91−log⁡S−273.15Arnorsson (1983)
    ChalcedonyT=10324.69−log⁡S−273.15Fournier (1977)

    (a), adiabatic.

      • View popup
      Table 2.

      Physical and chemical parameters of hot springs in the Mongolian Altai area

      IDT, °CpHORP, mVTDSDONaKCaMgHCO3CO3CISO4SiO2FIEB, %
      Mg l–1
      GM130.49.2140.01270.0745.41.232.020.2241.623.517.88.9146.79.860.121
      GM224.59.1859.11450.0345.41.232.210.2247.322.413.710.748.27.310.054
      CH122.09.2243.32210.5368.61.845.330.4272.615.17.7068.364.52.970.133
      CH223.89.2651.92300.0171.81.832.500.2474.615.27.3166.161.11.270.291
      CH321.39.1150.62590.3071.11.752.000.4968.717.89.6261.564.23.160.041
      CH424.79.1444.72250.4073.61.863.220.4178.015.98.1167.460.91.990.016
      CH524.79.1352.62250.4071.41.892.810.5479.412.57.1467.960.44.120.045
      AC131.09.0028.81870.3138.41.222.800.1050.518.63.4114.551.64.820.066
      AC235.08.6030.61880.2832.91.023.200.1648.714.62.6212.949.54.050.148
      AC332.08.6535.81740.4434.51.202.800.1048.115.72.3014.545.32.820.014
      IN125.08.401247250.4519612.524.21.221108.6547.732275.66.20.080
      IN228.08.321276980.6118615.222.21.2291.56.1247.731969.22.540.022
      • View popup
      Table 3.

      Correlations of major ions (milliequivalents per litre) in hot spring samples

      NaKCaMgHCO3SO4CISi
      Na1.00
      K0.961.00
      Ca0.960.981.00
      Mg0.930.900.891.00
      HCO30.760.560.590.671.00
      SO40.990.970.980.920.701.00
      CI0.980.950.940.940.590.931.00
      Si0.850.710.720.750.900.830.651.00

      f(X) = 0.96

        • View popup
        Table 4.

        Saturation indices for hot springs of the Mongolian Altai region

        SamplesGM1GM2CH1CH2CH3CH4CH5AC1AC2AC3IN1IN2
        Albite7.598.138.318.118.077.997.816.656.566.076.816.56
        Alunite−6.55−4.77−2.29−3.22−2.71−3.14−3.61−7.51−5.96−7.95−2.19−2.64
        Anhydrite−1.9−1.8−0.84−1.12−1.29−1.06−1.09−1.47−1.26−1.320.210.21
        Calcite2.342.372.622.392.182.42.322.412.282.232.62.44
        Fluorite2.562.451.930.881.591.311.92.152.171.812.982.14
        Gibbsite1.231.651.981.751.751.661.490.560.790.080.710.51
        Gypsum−1.66−1.49−0.51−0.08−0.94−0.75−0.79−1.23−1.07−1.090.510.48
        Halite−4.94−5.04−5.18−5.19−5.06−5.14−5.21−5.73−5.89−5.92−4.05−4.08
        K-feldspar8.549.149.329.19.098.978.87.667.57.118.117.93
        K-mica16.618.018.818.218.117.917.414.414.712.915.114.5
        Kaolinite7.978.999.478.979.078.828.496.637.115.837.026.6
        Quartz2.332.432.342.322.382.342.342.332.342.422.382.38
        • View popup
        Table 5.

        Major and minor element compositions of rock samples

        Sample IDMajor elements, %
        SiO2TiO2Al2O3Fe2O3CaOMgONa2OK2OMnOP2O5
        CH75.50.21312.52.341.150.2903.053.920.0330.067
        GM75.30.17612.72.540.740.4114.502.570.0360.034
        IN70.20.35213.83.042.270.7123.423.750.0620.119
        AC69.30.35513.64.322.691.232.782.410.0770.086
        Minor elements, mg kg–1
        BaCsRbSbSrZnZrVSeCr
        CH38648.01904017618.064.025.130.043.0
        GM28939.080.24011648.210416.230.039.0
        IN93642.01324042532.316435.053.039.0
        AC23530.01994070.218.136.015.330.033.0
        • View popup
        Table 6.

        Calculated normative minerals

        Normative mineralsVolume norm, %
        CHGMINAC
        Quartz39.4136.3729.6730.16
        Plagioclase31.8542.9541.0138.26
        Orthoclase24.5316.1423.9323.94
        Corundum0.890.830.190.04
        Hypersthene2.853.364.456.86
        Ilmenite0.240.190.390.39
        Magnetite0.090.100.120.17
        Apatite0.140.060.230.18
        • View popup
        Table 7.

        Correlation analysis results for CLR transformed sample compositions

        CO3(w)Ca(w)Cl(w)HCO3(w)K(w)Mg(w)Na(w)SO4(w)Al2O3(r)CaO(r)Fe2O3(r)K2O(r)MgO(r)MnO(r)Na2O(r)P2O5(r)SiO2(r)TiO2(r)
        CO3(w) 
        Ca(w)−0.36 
        Cl(w)−0.21−0.60 
        HCO3(w)0.92−0.12−0.57 
        K(w)−0.910.520.28−0.90 
        Mg(w)0.01−0.890.89−0.31−0.09 
        Na(w)0.46−0.980.410.28−0.670.77 
        SO4(w)−0.890.38−0.15−0.670.66−0.21−0.39 
        Al2O3(r)−0.450.92−0.25−0.350.72−0.65−0.980.30 
        CaO(r)−0.411.00−0.61−0.160.55−0.88−0.970.460.90 
        Fe2O3(r)0.090.87−0.560.220.21−0.84−0.84−0.120.830.83 
        K2O(r)−0.76−0.050.04−0.600.410.140.050.90−0.140.04−0.53 
        MgO(r)−0.060.88−0.400.040.39−0.75−0.90−0.060.910.840.98−0.48 
        MnO(r)−0.240.95−0.43−0.100.52−0.79−0.970.150.970.920.95−0.300.98 
        Na2O(r)0.10−0.700.95−0.290.020.900.53−0.44−0.36−0.73−0.51−0.22−0.40−0.48 
        P2O5(r)−0.720.87−0.47−0.440.70−0.70−0.850.790.770.900.510.460.550.70−0.70 
        SiO2(r)0.41−0.960.360.27−0.660.741.00−0.31−0.99−0.95−0.870.13−0.93−0.980.47−0.80 
        TiO2(r)−0.500.99−0.48−0.280.65−0.81−0.990.480.950.990.810.050.850.94−0.620.91−0.97 

        (w), water; (r), rock; f(x) = 0.91

          • View popup
          Table 8.

          Reservoir temperature (T, °C)

          Sample IDAverageQuartz(1)Quartzad(2)Chalcedony(3)Chalcedony(4)
          CH96.211111082.281.6
          GM82.496.898.268.266.5
          IN106.412111992.692.8
          AC84.498.810070.168.6

          (1, 2, 4) Fournier (1977); (3) Arnorsson (1983); ad, adiabatic.

            • View popup
            Table 9.

            Temperatures and depths of the hot springs

            Sample IDReservoir temperature (°С)Water circulation depth (m)
            CH96.23070
            GM82.42615
            IN1063410
            AC84.42680
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          Geochemistry: Exploration, Environment, Analysis: 21 (4)
          Geochemistry: Exploration, Environment, Analysis
          Volume 21, Issue 4
          November 2021
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          Hydrogeochemical characteristics and geothermometry of hot springs in the Altai region, Mongolia

          Bolormaa Chimeddorj, Dolgormaa Munkhbat, Battushig Altanbaatar, Oyuntsetseg Dolgorjav and Bolormaa Oyuntsetseg
          Geochemistry: Exploration, Environment, Analysis, 21, geochem2021-016, 25 October 2021, https://doi.org/10.1144/geochem2021-016
          Bolormaa Chimeddorj
          1Department of Chemistry, School of Arts and Sciences, National University of Mongolia, Ulaanbaatar 14201, Mongolia
          2Department of Chemical–Biology, School of Natural Science and Technology, Khovd University, Peace Avenue, 164300 Khovd Province, Mongolia
          Roles: [Data curation (Lead)], [Formal analysis (Lead)], [Investigation (Lead)], [Validation (Equal)], [Writing – original draft (Lead)], [Writing – review & editing (Lead)]
          • Find this author on Google Scholar
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          Dolgormaa Munkhbat
          3Department of Chemical and Biological Engineering, School of Engineering and Applied Sciences, National University of Mongolia, Ulaanbaatar 14201, Mongolia
          Roles: [Data curation (Equal)], [Formal analysis (Supporting)], [Investigation (Equal)], [Writing – original draft (Equal)], [Writing – review & editing (Equal)]
          • Find this author on Google Scholar
          • Find this author on PubMed
          • Search for this author on this site
          • ORCID record for Dolgormaa Munkhbat
          Battushig Altanbaatar
          4Mineral Resources and Petroleum Authority of Mongolia, Ulaanbaatar, Mongolia
          Roles: [Formal analysis (Supporting)], [Software (Supporting)], [Visualization (Supporting)], [Writing – original draft (Supporting)]
          • Find this author on Google Scholar
          • Find this author on PubMed
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          • ORCID record for Battushig Altanbaatar
          Oyuntsetseg Dolgorjav
          5Mongolian Academy of Sciences, Institute of Chemistry and Chemical Technology, Ulaanbaatar, Mongolia
          Roles: [Data curation (Supporting)], [Methodology (Supporting)], [Validation (Equal)], [Writing – review & editing (Supporting)]
          • Find this author on Google Scholar
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          Bolormaa Oyuntsetseg
          1Department of Chemistry, School of Arts and Sciences, National University of Mongolia, Ulaanbaatar 14201, Mongolia
          Roles: [Conceptualization (Lead)], [Data curation (Equal)], [Funding acquisition (Supporting)], [Methodology (Lead)], [Project administration (Lead)], [Supervision (Lead)], [Writing – original draft (Equal)], [Writing – review & editing (Supporting)]
          • Find this author on Google Scholar
          • Find this author on PubMed
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          • ORCID record for Bolormaa Oyuntsetseg
          • For correspondence: [email protected]

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          Hydrogeochemical characteristics and geothermometry of hot springs in the Altai region, Mongolia

          Bolormaa Chimeddorj, Dolgormaa Munkhbat, Battushig Altanbaatar, Oyuntsetseg Dolgorjav and Bolormaa Oyuntsetseg
          Geochemistry: Exploration, Environment, Analysis, 21, geochem2021-016, 25 October 2021, https://doi.org/10.1144/geochem2021-016
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